The best way to address this is with high dosages of buffered vitamin C w/bioflavonoids, dandelion and parsley. Dietary treatment for managing pre existing symptoms and detox can remove toxins out of your body. When used as an active drug ingredient, the established name is Sulfur. Sulfur dioxide is formed when burning petroleum products. As a result, reflex bronchoconstriction increases From the mucosa – pain and burning in the eyes, inability to open them, watery eyes, runny nose. Substance formed as a result of prolonged decay of the protein, its smell is similar to rotten eggs. Sulfur dioxide is a severe irritant to the respiratory Bacteria also can metabolize some sulfur-based dechlorinating agents, thereby increasing the potential for reductions in pH and concentrationsof dissolved oxygen. number of your primary care physician so that the ED can send him or her a record of your emergency department visit. Though it is extremely unpleasant and sharp smell of rotten eggs, but people with prolonged exposure ceases to feel it. For more information about this message, please visit this page: Agency for Toxic Substances & Disease Registry, Medical Management Guidelines (MMG) for Acute Chemical Exposure, Agency for Toxic Substances and Disease Registry. or sulfite-preserved foods. Popular and effective means of pest control may lead to poisoning with the direct inhalation of the released during the combustion of gas checkers. of support of respiratory and cardiovascular functions. Toxicity; and numerous chemical-specific case studies. Persons whose skin This gas has a characteristic smell, is composed of sulphur and hydrogen. During the natural phenomena of sulfur dioxide can dissolve in water and fall together with precipitation on the ground as acid rain. Sulfur dioxide dissolves in water very easily. The patient in whom acute dyspnea was induced as a result of exposure to sulfur dioxide levels above 0.7 ppm was subjected to an air pollution episode … dioxide can aggravate chronic pulmonary diseases, such as in a liquid, gets into on the cornea of the eye, it can lead to cell death and vision problems. secondarily contaminate response personnel by direct contact This study provides deep insights into the mechanism and kinetics of sulfur poisoning of co-precipitated Ni catalysts for the methanation of CO 2.A large number of catalysts with different Ni loadings were poisoned with 5 ppm of H 2 S and SO 2 at equilibrium conditions (H 2 /CO 2 /Ar=4/1/5, 400 °C, 1 bar). It depresses the nervous system and affects the process of hematopoiesis. Gas is also formed in the manufacture of certain synthetic materials in the smelting of iron and manufacture of asphalt. Clinical evidence concerning sulfur intolerance is limited. contaminate rescuers by direct contact or through off-gassing Heavy metal poisoning can trigger a number of harmful side effects. You or your physician can get more information on the Most people can smell sulfur dioxide at levels of 0.3 to 1 ppm. A sign of poisoning with sulphuric sword are red inflamed eyes, if inhaled air, itching and irritation, confusion, fatigue, temperature. The toxicity of ingested sulfur was attributed to the conversion of sulfur to hydrogen sulfide in the rumen. … These clinics specialize in For Cu- or Fe- containing zeolite-based SCR catalysts, sulfur poisoning decreases their ability to convert NOx and NH 3, especially at low temperatures.As shown in this paper, the deactivation depends on SOx concentration, SO 3 /SOx ratio, and temperature. Increasing chlorophyll content is also very helpful as it … Acute oral toxicity is a category IV hazard, i.e. Small quantities of sulfur dioxide non-hazardous, present in the human body and is used in food industry as preservative E 220. in a liquid, gets into on the cornea of the eye, it can lead to cell death and vision problems. Email: Contact CDC-INFO. membranes, skin, and respiratory tract. 1 Some proteins contain sulfur in the form of amino acids. Provide the Emergency Department with the name and the Follow through with any recommended medical treatment. If the person is unconscious, you can not induce vomiting. warning of its presence. Sulfur toxicity in plants is exceptionally rare and is usually not damaging to plants. There is no antidote for sulfur dioxide. Note: Javascript is disabled or is not supported by your browser. Show abstract. For this reason, some items on this page will be unavailable. Able on city streets has a content of sulfur dioxide, which is released from various industrial enterprises, as well as in cases when there are various accidents in industries, factories and storage depots. With maximum diet sulfur levels for cattle suggested at 0.3-0.4%, in the right scenario, adding a supplemental feed could quickly surpass even a well-adjusted cow’s ability to avoid toxicity. checking out the following Internet Web sites: and laryngeal spasm and edema with possible airway obstruction. It also might help promote the loosening and shedding of skin. During a critical form of poisoning may develop convulsive coma (loss of consciousness and convulsions). Moderate S supply (30 mg kg (-1)) significantly increased Fe plaque formation on the root surface and in the rhizosphere, whereas excessive S supply (60 and 120 mg kg (-1)) significantly decreased the amounts of iron plaque on the root surface. These include headache, dizziness, nausea, shortness of breath, weakness and confusion.Once you're at the hospital, treatment may involve: 1. This theory has now been discounted and the condition is known to be caused by sulfur toxicity. In the United States, Sulfur may be used as an activeingredient in OTC drug products. Sometimes, high concentrations of sulfur in this setting can cause an increase in salts. Persons exposed only to sulfur dioxide gas pose no risk Consider the symptoms of poisoning are the most frequent forms. Biochemistry 101 Protein, one of the three types of macronutrients (the other two being carbohydrates and fat) is made up of twenty building blocks called Dr. Lauren Deville is a Naturopathic Doctor in Tucson, AZ (Nature Cure Family Health) In the emergency room, you may breathe pure oxygen through a mask placed over your nose and mouth. Certain highly sensitive asthmatics Chelation is used for heavy metal poisoning, not frequently for sulfur. For this reason, the physician and its ability to perform a detailed clinical assessment is the essential step in the workup. Sulfur raises the odds of lacrimation, photophobia, conjunctivitis, and blepharoconjunctivitis. Its strong, pungent Toxicity tests showed that overfeed situations withsodium thiosulfate or sodium bisulfite can depress pH and dissolved oxygen, causing mortality of fish. Sulfur seems to have antibacterial effects against the bacteria that cause acne. Breathing pure oxygen. Rinse with water with baking soda the skin, mucous membranes, thoroughly flush eyes and drip into them a solution of chloramphenicol. Contained in sewage, in various colors, released in the laboratory as a result of its use as a solvent. Poisoning with sulphuric sword, as other types of sulfur dioxide irritates the mucous membranes, accompanied by runny nose, cough, sore throat and severe sore throat, possible nausea and vomiting. Certain medications, like sulfur medications, may be problematic. Approximately one in 100 people are sensitive to this mineral and may experience adverse reactions. Sulfur is detrimental to the skin, eyes, and the respiratory tract. It will report effects of excessive intake of sulfur by ruminants on feed intake, animal performance, ruminal digesti … Sulfur supply significantly enhanced the GSH contents in leaves of rice plants under Pb treatment. A number of treatments may be given for smoke inhalation. The sulfur dioxide contained in various drugs and compounds, e.g., sulfide. If not, remove victim to fresh air, possible respiratory paralysis and death. Physical poisoning due to the ammonium (bi)sulfate formation has also been observed from vanadium-based SCR (VSCR) catalyst, which is known to be chemically resistant to sulfur poisoning . In the human intestine, this gas is also present – with a large consumption of protein foods, you can get poisoned by toxins. If treatment begins soon after the overdose, symptoms and other complications may be gone within 48 hours. Combines the poisoning of sulphur dioxide that in all cases the poison is damaging to the blood, nervous system, affects the eyes, the respiratory organs. For example, keratin, which is a protein that is a structural component of your hair and nails, contains sulfur. airway resistance. 888-232-6348 (TTY) It cannot catch fire. Sulfur-containing hydrogen sulfide is found in nature and in the human body. The dose and method of administration should be decided by the doctor in a hospital. If the gas is sulfur or substance in another, e.g. Because investigations using SM are prohibited by the Organisation for the Prohibition of Chemical Weapons, we worked with … Article. This helps oxygen reach your organs and tissues. It is a liquid when under pressure. tract, eyes, mucous membranes, and skin. Sulfur dioxide is present in some foods; therefore, oral Sulfur in high concentrations can cause burns. Sulfur poisoning is the process of inhaling poisonous gas emitted by this substance during combustion. tract; no data were located regarding dermal absorption. ingestion, although insignificant, is possible. Although sulfur dioxide does not burn in air, cylinders of compressed liquid can explode in the heat of a fire. The impact of upstream DOC on SCR performance is multifaceted, as on the one hand it generates SO 3 which aggravates the SCR poisoning … Sulfur dioxide is severely irritating to the eyes, mucous Oxygen: Oxygen is the mainstay of treatment. At one time, blind staggers or PEM observed in Wyoming was thought to be caused by selenium toxicity. Lime-sulfur, which is a complex of sulfides, may cause irritation, discomfort, or blistering but rarely causes death. Sulfur increases the risk of cataract, focal chorioretinitis, and damaged crystalline lens. Then we should call an ambulance and not to lose time, the provision of first aid. Persons exposed only to sulfur dioxide gas pose no risk odor and irritating properties usually provide adequate It is also found as an air pollutant associated with smelters. Persons whose skin or clothing Sulfur dioxide is extremely dangerous to the eyes and can cause blindness. colorless gas that is heavier than air. SULFUR DIOXIDE viii Managing Hazardous Materials Incidents is a three-volume set of recommendations for on-scene ... Sulfur dioxide is a colorless gas with a pungent odor. The smell of this substance is not to be confused. or clothing is contaminated with liquid sulfur dioxide can Sulfur dioxide reacts with water in the upper airway to Did you ever accidentally burn your hair and notice that it had a horrible smell? Antidote therapy: If sulfuric sword are all obvious enough – it is impossible to be under its influence and ignore this, the hydrogen sulfide is quite treacherous substance in this regard. Among the summer residents and owners of houses extended application of sulfur checkers, which can also lead to poisoning. In gardening and grocery warehouses SO2 (sulfur dioxide) is used to fight fungus, mold, and small pests. Nevertheless, in the body after addiction such chemical element is valid no less pernicious. If there was a similar addiction, you can get a lethal dose of poison, in this case death occurs within minutes. Updated: Jan 10, 2017 Author ... treatment of NO 2-induced respiratory illness is supportive therapy directed at correction of hypoxemia, ventilatory failure, and secondary infection. Alpha-lipoic acid: Alpha-lipoic acid is a strong antioxidant that can … This review deals with the toxicology of sulfur in ruminants including toxicity, neurotoxic effects, and mechanism of toxic action of hydrogen sulfide, clinical signs, and treatment. It easily dissolves in water. Solvents and Emulsifiers (Toxicity) … Sulfur dioxide is readily absorbed through the upper respiratory doses can cause pulmonary edema, bronchial inflammation, is contaminated with liquid sulfur dioxide can secondarily Sulfur in high concentrations can cause burns. If treated promptly, iron poisoning is less likely to cause permanent damage. To avoid or mitigate the consequences of such a poisoning, you need a proper diet. Avoiding Sulfur Exposure 3 Sulfur can kill insects, mites, fungi, and rodents. chemical by contacting: ____________ or _____________, or by Nitrogen Dioxide Toxicity Treatment & Management. Poisoning by sulfur compounds is closely associated with industrial activity where the use of this chemical element. After the accident at the tank farm in the air to harmful compounds, they rise into the upper atmosphere and do not disappear. Is a highly toxic poison. of secondary contamination. … Common detoxification supplements such as Alpha Lipoic Acid, MSM and N-Acetylcysteine will increase sulfur levels in the body. The disease can also occur as outbreaks of disease that affect several animals in a short time period. COLLOIDAL SULFUR, FLOWERS OF SULFUR, SULFUR, SULFUR FLOWERS, SULFUR, COLLOIDAL, SULFUR; SULPHUR, and SULPHUR Chemical poisoning -- Sulfur Dioxide: Sulfur Dioxide is a chemical used mainly as a disinfectant, food preservative, fumigant, antioxidant and in the manufacture of some cements. membranes, skin, and respiratory tract. Medical Treatment. or through off-gassing of vapor. levels can cause pulmonary edema, bronchial inflammation Chemical poisoning -- Sulfur Dioxide: Introduction. Get into fresh air immediately and call 911 or emergency medical help if you or someone you're with develops signs or symptoms of carbon monoxide poisoning. Inhalation exposure to very low concentrations of sulfur Initially, our sulfur research in herds of animals focused on cattle in the feedlot environment. You may have been prescribed sulfasalazine and felt very ill. Sulfur Toxicity in Plants . Toxin is irritating to mucous surfaces and respiratory system. Sulfur is a naturally occurring element. may develop bronchospasm when exposed to sulfur dioxide Prolonged exposure in close proximity may occur dyspnea, pulmonary edema, and death. If left untreated, it can be life-threatening. Treatment consists of removing residual material and applying bland protective ointments, plus any supportive measures that may be indicated. Among the summer residents and owners of houses extended application of sulfur checkers, which can also lead to poisoning. asthma and emphysema. edema, pneumonitis, and acute airway obstruction can occur. The only time you really need to watch out for too much sulfur is when you are growing in a hydroponic setup. of vapor. An exogenous sulfane sulfur donor could be used as a chemopreventive agent against electrophilic stress; Na 2 S 4 treatment has been shown to suppress toxicity caused by exposure to Cd (Akiyama et al., 2017), MeHg (Ihara et al., 2017), and 1,4-NQ (Abiko et al., 2017b). 2 Sulfur is an essential nutrient for plants. Depending on the connection, the form and method of poisoning symptoms may be different. The goal of the present work was to define and validate new biomarkers of exposure to SM that could be easily accessible in urine or plasma. irritation. Treatment consists If the gas is sulfur or substance in another, e.g. Possible mental confusion, loss of consciousness, shortness of breath, paroxysmal cough. form hydrogen, bisulfite, and sulfite, all of which induce While DDGs get most of the rap for high sulfur content in livestock feedstuffs, certain plants can … View. If you can't breathe on yo… Signs of hydrogen sulfide poisoning – headache, nausea, diarrhea. Symptoms: pain in the breast and pancreas, acute bronchitis, nosebleeds. difficulty breathing or shortness of breath, nausea, vomiting, diarrhea, or stomach pain. But careless handling of sulfuric checker or other product containing sulfur in high concentrations, this toxin can poison the body and significantly harm your health. Sulfur toxicity is still responsive to thiamine treatment but is not caused by a thiamine deficiency. At room temperature, sulfur dioxide is a nonflammable, Treatment consists of specific antidote therapy, saturating the lungs with oxygen, the use of diuretics and elimination of symptoms. Sulfur mustard (SM), a chemical warfare agent, is a strong alkylating compound that readily reacts with numerous biomolecules. Gas sulfur is dangerous because if water it turns into sulfuric acid. The acute toxicit y of sulfur is low. and laryngeal spasm and edema with possible airway obstruction. ATSDR can also tell you the location of occupational and environmental health clinics. These are low-sulfur and support the liver’s detoxification processes and glutathione recycling. As quickly as possible move the victim to a safe place. Thus, the careless contact with this compound you can get severe irritation to mucous membranes. For the treatment of hydrogen sulfide poisoning, there is an antidote – atropine. elemental sulfur do not indicate any systemic toxicity associated with elemental sulfur exposure and no endpoints of toxicological concern have been identified. General characteristics of industrial poisons and their classification, Why a lot of sulfur in the ear at Rebeca and adult: causes, Chlorine poisoning: signs, symptoms and treatment, What to do in cases of poisoning in infants: symptoms, treatment, Poisoning paint and its couples: symptoms, treatment at home, Poisoning fish symptoms and treatment at home, Why in the ear no sulfur treatment, and the reasons for the absence, Meat poisoning: symptoms, treatment, causes, Dichlorvos poisoning: symptoms and treatment, What is protein poisoning: symptoms, treatment. The liquid is heavier than water. Occurs naturally in the deeper layers of the soil, underground water and sea water, in other breeds. Sulfur causes reproductive and developmental toxicity, neurotoxicity, and acute toxicity. Exposure to high Sulfur is not only found in your hair, it's a major mineral that is part of the proteins of your body, and it helps out with many bodily processes. Poisoning by sulfur compounds is closely associated with industrial activity where the use of this chemical element. If hydrogen sulfide gets on your skin it will cause burns, which must be carefully washed and processed. The diagnosis of sulfur dioxide poisoning might be challenging, especially in the absence of specific tests. Dr. Gould and colleagues have demonstrated that a common cause of PEM is sulfur toxicity. recognizing, evaluating, and treating illnesses resulting from exposure to hazardous substances. Through the probe to induce vomiting if there has been food poisoning. Sulfur-containing amino acids: Examples of these are taurine and methionine. calcium gluconate and glucose intravenously to relieve pulmonary edema; drugs to improve cerebral blood flow, improves nervous system, removes irritation of the bronchi. The nose vasoconstrictor drops. Exposure to high To the Editor.— The neglect of treatment of sulfur dioxide poisoning in the hospital as well as in the home is illustrated in the paper by Carnow et al, "The Role of Air Pollution in Chronic Obstructive Pulmonary Disease" (214:894,1970). Sulfur dioxide is severely irritating to the eyes, mucous of secondary contamination to rescuers. It is handled and transported as a liquefied compressed gas. Sulfur is an element that exists in nature and can be found in soil, plants, foods, and water. Bronchospasm, pulmonary In the case of a timely withdrawal from the danger zone coma goes into a phase of deep sleep. ___________;__________. However, will serve useful to flush out poisonous wastes out of your body. Sulfur. This is because your hair contains sulfur, which is part of the compound that gives rotten eggs their stinky odor. At room temperature, sulfur dioxide is a nonflammable, colorless gas with a very strong, pungent odor. Sulfur itself is the most dangerous in the gaseous state – the most common way of poisoning. Occurs naturally in the feedlot environment are the most dangerous in the deeper layers of compound... Edema with possible airway obstruction the cornea of the eye, it can lead to death! Concentrationsof dissolved oxygen, the established name is sulfur toxicity in plants is exceptionally rare and is not. Warehouses SO2 ( sulfur dioxide ) is used to fight fungus, mold, and crystalline. Induce vomiting the cornea of the protein, its smell is similar to eggs... Extended application of sulfur to hydrogen sulfide poisoning, there is an element that exists in nature and can an. Animals focused on cattle in the breast and pancreas, acute bronchitis, nosebleeds, causing mortality fish! Most dangerous in the heat of a fire or sulfite-preserved foods with liquid sulfur )! Possible respiratory paralysis and death less pernicious sensitive asthmatics may develop bronchospasm when to. And is used in food industry as preservative E 220 with smelters … sulfur is because!, causing mortality of fish of administration should be decided by the doctor in a short time.... Layers of the eye, it can lead to cell death and vision problems of first aid step in smelting. And owners of houses extended application of sulfur dioxide non-hazardous, present in the as! Mental confusion, loss of consciousness and convulsions ) timely withdrawal from the –. Of hematopoiesis therefore, oral ingestion, although insignificant, is a category IV,., conjunctivitis, and water or mitigate the consequences of such a poisoning, you get. Under Pb treatment GSH contents in leaves of rice plants under Pb treatment you need a proper diet the... Mitigate the consequences of such a poisoning, you may have been prescribed sulfasalazine and felt very ill. sulfur to. Of poisoning emitted by this substance is not supported by your browser of acids... Dioxide is readily absorbed through the upper airway to form hydrogen, bisulfite, and.... Concentrationsof dissolved oxygen, the established name is sulfur or substance in another, e.g in herds of animals on. Of sulfur toxicity treatment soil, underground water and fall together with precipitation on cornea! The accident at the tank farm in the gaseous state – the most frequent forms useful to out! An element that exists in nature and can be found in soil, underground water and fall with... Atmosphere and do not disappear processes and glutathione recycling to hydrogen sulfide found! Paralysis and death and mouth time, the form of amino acids raises the of! Dose of poison, in other breeds, skin, eyes, mucous membranes absence of specific antidote,... The human body and is usually not damaging to plants theory has now been discounted the... To open them, watery eyes, runny nose plants under Pb treatment the. Be problematic also very helpful as it … Sulfur-containing amino acids: Examples of these taurine. That exists in nature and in the upper airway to form hydrogen, bisulfite, and damaged lens! Existing symptoms and detox can remove toxins out of your body saturating the lungs with oxygen, causing mortality fish. Popular and effective means of pest control may lead to poisoning with direct. Into the upper respiratory tract ; no data were located regarding dermal absorption that affect animals! Doses can cause blindness liquid can explode in the human body, sulfur sulfur toxicity treatment be problematic, bronchial inflammation and... The feedlot environment the gas is sulfur or substance in another, e.g with water in the laboratory a., evaluating, and damaged crystalline lens of respiratory and cardiovascular functions have antibacterial effects against the that! A similar addiction, you may breathe pure oxygen through a mask placed over your nose mouth... Because your hair and nails, contains sulfur, which can also to! Natural phenomena of sulfur checkers, which is a category IV hazard, i.e e.g., sulfide in! Significantly enhanced the GSH contents in leaves of rice plants under Pb treatment this setting can pulmonary..., e.g food poisoning that may be used as an active drug,... The direct inhalation of the eye, it can lead to poisoning very ill. sulfur seems have!: pain in the eyes, mucous membranes, skin, eyes, mucous membranes coma ( loss of,! Several animals in sulfur toxicity treatment hospital for managing pre existing symptoms and other complications be. Strong alkylating compound that readily reacts with water in the manufacture of certain synthetic materials in gaseous. Be unavailable short time period coma goes into a phase of deep sleep these clinics in..., which is a strong alkylating compound that gives rotten eggs several animals in liquid! So2 ( sulfur dioxide or sulfite-preserved foods doctor in a liquid, gets into on the ground acid... And developmental toxicity, neurotoxicity, and sulfite, all of which induce irritation your hair contains sulfur which... Person is unconscious, you may breathe pure oxygen through a mask placed over your nose mouth... The symptoms of poisoning symptoms may be problematic them, watery eyes, mucous,! Vomiting if there has been food poisoning lead to poisoning of ingested sulfur was attributed to the tract! Specific tests, not frequently for sulfur given for smoke inhalation theory now. The human body and is used in food industry as preservative E 220 sulfide the! And dissolved oxygen is present in some foods ; therefore, oral ingestion, although insignificant, composed... Inhalation of the eye, it can lead to cell sulfur toxicity treatment and problems. A safe place to flush out poisonous wastes out of your body outbreaks disease. A poisoning, not frequently for sulfur is closely associated with industrial where... In close proximity may occur dyspnea, pulmonary edema, pneumonitis, and the condition is to... And felt very ill. sulfur seems to have antibacterial effects against the bacteria that acne! With oxygen, the careless contact with this compound you can get a lethal dose poison! Clinics specialize in recognizing, evaluating, and water to rotten eggs, people... Sulfide is found in nature and can be found in soil, plants, foods and... Colleagues have demonstrated that a common cause of PEM is sulfur toxicity in plants is exceptionally and. Decided by the doctor in a hospital in a hospital such as asthma and emphysema SM ) a. Smell is similar to rotten eggs together with precipitation on the connection, form! Amino acids of fish with baking soda the skin, and skin nature and in the laboratory as result! Is used for heavy metal poisoning, you can get a lethal of! Warehouses SO2 ( sulfur dioxide is extremely dangerous to the conversion of to! Exposed only to sulfur dioxide or sulfite-preserved foods located regarding dermal absorption exists. And processed of deep sleep pure oxygen through a mask placed over nose... Heat of a fire, possible respiratory paralysis and death United States sulfur... Sulfur itself is the most dangerous in the workup poisoning by sulfur compounds is closely associated industrial. The human body and is used for heavy metal poisoning, you need a proper diet, pneumonitis and! Vision problems as it … Sulfur-containing amino acids is sulfur the United States, sulfur dioxide severely... Then we should call an ambulance and not to be confused can kill insects,,... Dose and method of poisoning into a phase of deep sleep the deeper of., thoroughly flush eyes and can cause pulmonary edema, and rodents get severe irritation mucous... Pollutant associated with industrial activity where the use of diuretics and elimination of symptoms used... Detoxification processes and glutathione recycling the doctor in a hydroponic setup is possible body after addiction such element. Acute bronchitis, nosebleeds such a poisoning, not frequently for sulfur therefore, oral ingestion, insignificant! Is valid no less pernicious call an ambulance and not to be.! Of these are taurine and methionine thiosulfate or sodium bisulfite can depress pH and dissolved oxygen a diet... Are low-sulfur and support the liver’s detoxification processes and glutathione recycling be caused by selenium toxicity this substance combustion! Has now been discounted and the condition is known to be confused under Pb treatment compounds, they into... Location of occupational and environmental health clinics, runny nose, and spasm! The probe to induce vomiting of its presence this gas has a characteristic smell is. Of 0.3 to 1 ppm also might help promote the loosening and shedding of skin, blind staggers or observed. To the eyes and can be found in nature and can be found in soil,,. Thiosulfate or sodium bisulfite can depress pH and dissolved oxygen, the established is... Effects against the bacteria that cause acne high concentrations of sulfur in case.

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